Direct one-step synthesis of trifluoromethyl iodide

Details Direct one-step synthesis of trifluoromethyl iodide Direct one-step synthesis of trifluoromethyl iodide

2007-03-27

2007-03-27

Parsa, J. (Department: 1621)

Organic compounds -- part of the class 532-570 series

Organic compounds

Halogen containing

C570S243000

Reexamination Certificate

active

11007019

ABSTRACT:
A catalytic one-step process for the production of CF3I by reacting, in the presence of a source of oxygen, a source of iodine a reactant of the formula:in-line-formulae description="In-line Formulae" end="lead"?CF3Rin-line-formulae description="In-line Formulae" end="tail"?where R is —COOH, —COX, —CHO, —COOR2and —SO2X, where R2is an alkyl group and X is selected from chlorine, bromine and iodine. The catalyst may be a metal salt such as salts of Cu, Hg, Pt, Pd, Co, Mn, Rh, Ni, V, Tl, Ba, Cs, Ca, K and Ge and mixtures thereof, preferably on a support, such as MgO, BaO and CaO, BaCO3, CsNO3, Ba (NO3)2, activated carbon, basic alumina, and ZrO2.

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