Direct electrochemical conversion of carbon to electrical energy

Chemistry: electrical current producing apparatus – product – and – Having magnetic field feature

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429 20, 429 33, 429218, H01M 812

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active

053764692

ABSTRACT:
A high temperature fuel cell (10) having first and second temperature zones (14, 16) for directly converting carbon fuel (12) to electrical energy comprises a first heat source (22), a second heat source (26), and a housing (18) that includes a non-porous section (15) and a solid electrolyte (30) having first and second electrolyte surfaces (32, 34) to which first and second electrodes (36, 38) are electrically connected. The first heat source (26) establishes first temperature zone (14) in the vicinity of the solid electrolyte (30) for adjusting the conductivity of the solid electrolyte (30) and electrodes (36, 38). The second heat source (26) is positioned in the vicinity of non-porous section (15) of housing (18) a distance from first heat source (22) to establish second temperature zone (16). A fuel compartment (20) defined by the first electrolyte surface (32) of solid electrolyte (30) and the non-porous section (15) of housing (18) spans first and second temperature zones (14, 16) to allow intermixing of oxygen provided through solid electrolyte (30) and a carbon fuel (12) which is located primarily in second temperature zone (16). The fuel compartment (20) may be provided with a gas inlet (25), gas outlet (27), and return line (31) through which non-reactive gas can be circulated to enhance the mixing of oxygen with carbon fuel (12). To generate electrical power, second temperature zone (16) is adjusted to a temperature which favors the complete oxidation of carbon fuel (12), first temperature zone (14) is adjusted to a temperature that minimizes the resistance of solid electrolyte (30) and electrodes (36, 38), and oxygen is provided by supplying an oxygen containing gas to the second electrolyte surface (32) of solid electrolyte (30).

REFERENCES:
patent: 460122 (1891-09-01), Edison
patent: 4404068 (1983-09-01), Huggins et al.
patent: 4459340 (1984-07-01), Mason
patent: 4921765 (1990-05-01), Gmeindl et al.
patent: 5232793 (1993-08-01), Miyauchi et al.
patent: 5298340 (1994-03-01), Cocks et al.
Turgut M. Gur and Robert A. Huggins, "Direct Electrochemical Conversion of Carbon to Electrical Energy in a High Temperature Fuel Cell," Journal of Electrochemical Society, vol. 139, No. 10, Oct. 1992, pp. L95-L97.
Turgut M. Gur, Ian D. Raistrick and Robert A. Huggins, "Steady-State D-C Polarization Characteristics of the O.sub.2, Pt/Stabilized Zirconia Interface," Journal of Electrochemical Society, vol. 127, No. 12, Dec. 1980, pp. 2620-2628.
"Solid oxide fuel cells to be developed," Chemical & Engineering News, p. 24, Jun. 10, 1991.
"Scaleup slated for ceramic fuel cell," Chemical & Engineering News, p. 21, APr. 28, 1986.
Jack T. Brown, "High Conductivity Solid Ionic Conductors: Recent Trends and Applications," T. Takahashi (ed.), World Scientific, Singapore, 1989, pp. 630-663 (Month unknown).
J. Weissbart and R. Ruka, "Solid Oxide Electrolyte Fuel Cells," American Chemical Society 140th Meeting in Chicago, vol. II, G. J. Young (ed.), Reinhold Publishing Corp., New York 1963 (Month unknown).
J. Weissbert and R. Ruka, "A Solid Electrolyte Fuel Cell," Journal of Electrochemical Society, vol. 109, No. 8, 1962, pp. 723-726 (Month unknown).
E. Baur and H. Preis, "Uber Brennstoff-Ketten Mit Festleitern," Ztschr. Elektrochem, Bd. 43, No. 9, Jun. 1937, pp. 727-732.
D. H. Archer and R. L. Zahradnik, "The Design of a 100-Kilowatt, Coal Burning, Fuel Cell Power System," Chem. Eng. Progr. Symp. Series, No. 75, vol. 63, 1967 pp. 55-62 (month unknown).
B. C. Nguyen, T. A. Lin and D. M. Mason, "Electrocatalytic Reactivity of Hydrocarbons on a Zirconia Electrolyte Surface," Journal of Electrochemical Society, vol. 133, No. 9, pp. 1807-1815, Sep., 1986.
Turgut M. Gur, Excerpts from "Electrochemical Reduction of Oxygen and Nitric Oxide on Stabilzed Zicronia," Dissertation Submitted to the Department of Materials Science and Engineering and the Comittee on Graduate Studies of Stanford University, Apr. 1976.
D. Eng and M Stoukides, "Catalytic and Electrocatalytic Methane Oxidation with Solid Oxide Membranes," Catal. Rev. Sci. Eng. 33 (3&4) p. 375, 1991 (Month unknown).
"Dual design for `coal-fired` fuel cells," Science News, Nov. 7, 1992, vol. 142, p. 318.
T. M. Gur, I. D. Raistrick and R. A. Huggins, "Ionic Conductivity of 8mol.%Sc.sub.2 O.sub.3 -ZrO.sub.2 Measured by Use of Both A.C. and D.C. Techniques," Materials Science and Engineering, vol. 46, 1980, pp. 53-62 (month unknown).

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