Direct conversion of natural gas to methanol by controlled oxida

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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422208, 568910, C07C 2948

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active

046187324

ABSTRACT:
A process of directly converting natural gas to methanol employs controlled oxidation. The reaction takes place in an inert reactor, i.e. one having internal surfaces which do not affect the reaction, in the absence of a catalyst. The natural gas is intimately mixed with air or oxygen prior to introduction of the mixed gases into the reactor. Reaction takes place at an elevated temperature of 300.degree. to 500.degree. C. and at an elevated pressure of 10 to 100 atmospheres. The percentage of oxygen in the mixture of reactant gases is kept below 20% by volume and is preferably 2 to 10% by volume. Apparatus for carrying out the method is also provided.

REFERENCES:
patent: 1976790 (1934-10-01), Lewis et al.
patent: 2004714 (1935-06-01), Thompson et al.
patent: 2042134 (1936-05-01), Walker
patent: 2128909 (1938-09-01), Bludworth
patent: 3092667 (1963-06-01), Murphy
patent: 4243613 (1981-06-01), Brockhaus et al.
Perry et al., "Perry's Chemical Engineers Handbook", 4th ed., 1963, 21-3 and 21-4.
The Direct Conversion of Methane to Methanol--Proceedings of the VI International Symposium on Alcohol Fuels Technology, Ottawa, Canada, May 21-25, 1984.

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