Diorganosilacetylene-alt-diorganosilvinylene polymers and a proc

Compositions: ceramic – Ceramic compositions – Carbide or oxycarbide containing

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525275, 525288, 5253265, 526279, C04B 35565

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054570743

ABSTRACT:
The present invention provides linear organosilicon polymers including acetylene and vinylene moieties, and a process for their preparation. These diorganosilacetylene-alt-diorganosilvinylene linear polymers can be represented by the formula: --[--(R.sup.1)(R.sup.2)Si--C.tbd.C--(R.sup.3)(R.sup.4)Si--CH.dbd.CH--].sub .n --, wherein n.gtoreq.2; and each R.sup.1, R.sup.2, R.sup.3, and R.sup.4 is independently selected from the group consisting of hydrogen, halogen, alkyl, alkenyl, aryl, and aralkyl radicals. The polymers are soluble in organic solvents, air stable, and can be pulled into fibers or cast into films. They can be thermally converted into silicon carbide ceramic materials.

REFERENCES:
patent: 4100233 (1978-07-01), Yajima et al.
patent: 4117057 (1978-09-01), Yajima et al.
patent: 4374793 (1983-02-01), Koga et al.
patent: 4595472 (1986-06-01), Haluska
patent: 4800221 (1989-01-01), Marko
patent: 4806612 (1989-02-01), Chandra et al.
patent: 4923949 (1990-05-01), Iwahara et al.
patent: 4940767 (1990-07-01), Barton et al.
patent: 4965332 (1990-10-01), Barton et al.
patent: 4996341 (1991-02-01), Iwahara et al.
patent: 5162478 (1992-11-01), Barton et al.
patent: 5196235 (1993-03-01), Parlier et al.
S. Nitta et al., "Structural and Electronic properties of polymeric amorphous semiconductors Si.sub.1-x C.sub.x :H", Chemical Abstracts, 107, 856 (1987), Abstract No. 107:166920c.
Y. Pang, "Exploring novel silicon-containing polymers, from preceramic polymers to conducting polymers with nonlinear optical properties", Dissertation, Iowa, State University, Ames, Iowa (1990).
R. W. Rice, "Ceramics from Polymer Pyrolysis, Opportunities and Needs--A Materials Perspective," Ceramics Bulletin, 62, 889-892 (1983).
M. G. Voronkov et al., "Si-Methyl (fluoro)-Substituted Derivatives of trans-1, 2-Disilylethylene", English translation of article in Izv. Akad. Nauk SSR, Ser. Khim., No. 8, 1911 (1981).
M. G. Voronkov et al., Metalloorg. Khim., 2, 463 (1989) ("Silicon-Substituted disilylacetylenes containing silicon-hydrogen bonds and their conversion to macrocyclic systems", Chem. Abs., 111, 805 (1989), Abstract No. 111:232965g).
R. West et al., "Polysilastyrene: Phenylmethylsilane-Dimethylsilane Copolymers as Precursors to Silicon Carbide," Ceramic Bulletin, 62, 899-903 (1983).
O. G. Yarosh et al., "Reaction of Trimethyl (Bromomagnesiumethylnyl)Silane with Organyltrialkoxysilanes", English translation of article in Izv. Akad. Nauk SSR, Ser. Khim., No. 11, 2637 (1985).
O. G. Yarosh et al., Metalloorg. Khim., 1, 773 (1988) ("Organo [.beta.-(trifluorosilyl)vinyl]silanes", Chem. Abs., 111, 783 (1989), Abstract No. 111:194839j).
O. G. Yarosh et al., Metalloorg. Khim., 2, 515 (1989) ("Disilylacetylenes halo-substituted on silicon", Chem. Abs., 112, 763 (1990), Abstract No. 112:98624k).
S. Yajima, "Silicon Carbide Fibres", (Chapter IV of Strong Fibers, V. Walt et al., eds., North Holland, Amsterdam, 1985; pp. 201-237).
T. J. Barton et al., "Organosilicon Chemistry: A Brief Overview" in Silicon-Based Polymer Science: A Comprehensive Resource, American Chemical Society: Washington, D.C.; Chap. 1, pp. 3-46 (1990).
T. J. Barton et al., "Thermal and Catalytic Polymerization of Diethynyldiphenylsilane," Macromolecules, 24, 1257-1260 (1991).
I. M. Gverdtsiteli et al., Soobschch. Akad. Nauk. Gruz. SSR, 66, 77 (1972).
S. Ijadi-Maghsoodi et al., "Synthesis and Study of Silylene-Diacetylene Polymers," Macromolecules, 23, 4485-4486 (1990).
S. Ijadi-Maghsoodi et al., "Efficient, `One-Pot` Synthesis of Silylene-Acetylene and Disilylene-Acetylene Preceramic Polymers from Trichloroethylene," J. Polymer Science: Part A: Polymer Chemistry, 28, 955-965 (1990).
Metalloorg. Khim., 1, 712-713 (1988).

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