Diolefin dimerization using nitrosyl halides of iron triad metal

Details Diolefin dimerization using nitrosyl halides of iron triad metal Diolefin dimerization using nitrosyl halides of iron triad metal

1977-07-20

1979-03-13

O'Keefe, Veronica

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

252429R, 423386, C07C 302

Patent

active

041442784

ABSTRACT:
Nitrosyl halides of iron and cobalt are prepared by reacting dihalides of iron and cobalt with alkali metal nitrite. Nitrosyl halides of nickel are prepared by reacting nickel dihalide with alkali metal nitrite and nickel or zinc powder. The production of ligand-containing nitrosyl halides of iron, cobalt and nickel is also disclosed. Also disclosed is diolefin dimerization using a nitrosyl halide and elemental manganese, zinc or tin.

REFERENCES:
patent: 3377397 (1968-04-01), Maxfield
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patent: 3448129 (1969-06-01), Maxfield
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patent: 3655793 (1972-04-01), Myers
patent: 3767593 (1973-10-01), Myers
patent: 3917730 (1975-11-01), Katcheuko
patent: 3957894 (1976-05-01), Saeki et al.
R. Bruce King, Organo Metallic Syntheses, Academic Press, pp. 165-168, 1965.

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