Dimetronidazole phosphates

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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548338, C07F 965

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active

045310041

ABSTRACT:
This invention pertains to novel processes for preparing phosphorus derivatives of metronidazole. The invention is also particularly directed to the use of novel chloro containing phosphorus derivatives of metronidazole as intermediates in these processes. Furthermore, the intermediates are compounds which insofar as is presently known no one has previously prepared. Finally, the phosphorus derivatives of metronidazole prepared by the novel processes of the invention include novel analogs thereof.

REFERENCES:
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Cremlyn, R. J. W. et al., "A Simple Phosphorylation Procedure for Cyclic Alcohols", Synthesis, pp. 648-650, (1971).
Lacey et al., "A Simple Synthesis of Choline Alkyl Phosphates", Tetrahedron Letters, vol. 21, pp. 2017-2020 (1980).
Postescu, I. D. et al., "Characterization of Metronidazole-Phosphate, A Water Soluble Metronidazole Derivatives, as a Radiosensitizer of Hypoxic Cells", Strahlentherapie, 155, pp. 358-361 (1979).
Hoffer, M. et al., "Synthesis and Antiprotozoal Activity of 1-(3-Chloro-2-Hydroxypropyl)-Substituted Nitroimidazoles", J. Medicinal Chemistry, vol. 17, No. 9, pp. 1019-1020 (1974).
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