Dimethylacrylamide-copolymer hydrogels with high oxygen permeabi

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526279, 526286, C08F 2022

Patent

active

049545876

ABSTRACT:
This invention describes polymers which are obtained by copolymerization of 15-85 wt % N,N-dimethylacrylamide with about 15-85% of a fluorinated monomer such as perfluoroalkyl-alkylene acrylate or methacrylate with from 3 to 25 fluorine atoms and optionally, 0-50 wt % other acrylates or methacrylates and 0-20 wt %, but not more than 5 mol % of a polyvinyl functional crosslinking agent. These polymers are machinable in the dry state and form clear hydrogels with about 25-75 wt % water content and which possess oxygen-permeabilities 3-7 times higher than conventional hydrogels of similar water content. In the absence of crosslinking, the novel polymers are plasticized by water, forming clear hydroplastics with 30-70 wt % water content. The crosslinked polymers are especially useful for fabricating contact lenses for extended wear by either cutting and polishing a xerogel button, or by spin casting or direct molding in bulk or in solution.

REFERENCES:
patent: 4540761 (1985-09-01), Kawamura et al.
patent: 4735990 (1988-04-01), Kihara et al.

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