Dimethyl ether synthesis catalyst

Catalyst – solid sorbent – or support therefor: product or process – Regenerating or rehabilitating catalyst or sorbent – Gas or vapor treating

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502 73, 502208, 502244, 502302, 502342, B01J 2104, B01J 2306, B01J 2372

Patent

active

044231555

ABSTRACT:
A new catalyst and process for synthesis of dimethyl ether from low H.sub.2 /CO ratio syngas are disclosed. The catalyst is a combination of Cu, Zn and Al, co-precipitated in predetermined relative amounts, which is found to be oxidatively regenerable and utilizable with the syngas product of modern coal gasifiers without the need for external water-gas-shift.

REFERENCES:
patent: 3790505 (1974-02-01), Casey et al.
patent: 3925258 (1975-12-01), Cox
patent: 3988259 (1976-10-01), Ray
patent: 4011275 (1977-03-01), Zahner
patent: 4098809 (1978-07-01), Pagani
patent: 4111847 (1978-09-01), Stiles
patent: 4126581 (1978-11-01), Sugier et al.
patent: 4177167 (1979-12-01), Manara et al.
Herman et al., Catalytic Synthesis of Methanol from CO/H.sub.2, J. of Catalysis, 56, pp. 407-429 (1979).

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