Dimerizing acrylates to hexenedioates using ruthenium compound c

Details Dimerizing acrylates to hexenedioates using ruthenium compound c Dimerizing acrylates to hexenedioates using ruthenium compound c

1983-02-28

1984-11-27

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

502154, 502169, 502170, 502230, 502328, 502330, 562598, C07C 67343

Patent

active

044852568

ABSTRACT:
Process for dimerizing alkyl acrylate esters to dialkyl hexenedioates in the presence of an alkali metal-treated or alkaline earth metal-treated ruthenium compound. The hexenedioate products are useful to prepare adipic acid.

REFERENCES:
patent: 2244645 (1941-06-01), Jacobson
patent: 3013066 (1961-12-01), Alderson
patent: 3074999 (1963-02-01), Rauhut
patent: 3227745 (1966-01-01), McClure
patent: 3322819 (1967-05-01), Schreyer
patent: 3548021 (1970-12-01), Brattesani
patent: 3946066 (1976-03-01), Todd
patent: 3956358 (1976-05-01), Onsager
Alderson, Jenner and Lindsey, J. Am. Chem. Soc., 87, 5638, (1965).

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