Dimerization of norbornadiene to Binor-S with a homogeneous cata

Details Dimerization of norbornadiene to Binor-S with a homogeneous cata Dimerization of norbornadiene to Binor-S with a homogeneous cata

1976-08-13

1980-06-17

Sebastian, Leland A.

Chemistry of hydrocarbon compounds

Alicyclic compound synthesis

Polycyclic product

60208, C07C 321

Patent

active

042083559

ABSTRACT:
Binor-S is prepared by the catalytic dimerization of norbornadiene (bicyclo[2.2.1]hepta-2,5-diene) using a homogeneous catalyst system of cobaltic acetylacetonate and diethylaluminum chloride and triphenyl phosphine. Ethylaluminum dichloride or aluminum ethylsesquichloride can be used in lieu of the diethylaluminum chloride. The reaction rate is rapid at an ambient temperature. Binor-S can be used as a precursor for hydrocarbons having utility as a high energy fuel.

REFERENCES:
patent: 3113424 (1963-12-01), Wineman
patent: 3147589 (1964-09-01), James

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