Dimerization and/or dehydrogenation of alkanes

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By dehydrogenation

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585661, 585662, 502 51, 502 38, C07C 5327, C07C 5333

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active

052275655

ABSTRACT:
Barium peroxide oxidizer, together with a transition metal from Group I, III, IV, V, VII or VIII or compound thereof is used as stoichiometric reagent in the oxidative dimerization of hydrocarbons having three or four carbon atoms. Barium peroxide oxidizer, together with a transition metal from Group I, III, IV, V, VI, VII or VIII or compound thereof is used as stoichiometric reagent in the dehydrogenation of hydrocarbons having three or four carbon atoms.

REFERENCES:
patent: 4172810 (1979-10-01), Mitchell, III et al.
patent: 5073657 (1991-12-01), Warren
patent: 5073664 (1991-12-01), Durante et al.
Otsuka et al., Journal of Catalysis (1990) 121, 122-130.

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