Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymerizing in tubular or loop reactor
Reexamination Certificate
1999-03-09
2001-07-17
Wu, David W. (Department: 1713)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymerizing in tubular or loop reactor
C526S068000, C526S070000, C422S132000, C528S501000
Reexamination Certificate
active
06262191
ABSTRACT:
BACKGROUND OF THE INVENTION
This invention relates to the polymerization of monomers in a liquid diluent.
Addition polymerizations are frequently carried out in a liquid which is a solvent for the resulting polymer. When high density (linear) ethylene polymers first became commercially available in the 1950's this was the method used. It was soon discovered that a more efficient way to produce such polymers was to carry out the polymerization under slurry conditions. More specifically, the polymerization technique of choice became continuous slurry polymerization in a pipe loop reactor. Subsequent to the polymerization, the polymer must be separated from the diluent and the diluent recovered for recycle.
Preferably the solid catalyst for such reactions is first combined with diluent and the resulting catalyst mud introduced into the reactor.
Both environmental sensitivity and economics dictate that as little waste as possible occurs in such processes. Accordingly, modern slurry plants “lose” so little diluent during the separation and diluent recovery process that only a minute amount of “make-up” diluent is required. Indeed, so little make-up diluent is needed that the make-up diluent is of insufficient quantity to produce the catalyst mud. Hence recycle diluent must be used. However, recycle diluent unavoidably contains some unreacted monomer dissolved in it. While some monomer can be tolerated, it is greatly preferred to have monomer-free diluent for this step. Further complicating the polymer separation and diluent recovery is the presence of small amounts of other undesirable compounds in the recycle diluent such as alkanes other than the diluent, olefins other than the monomer or monomers, very low molecular weight oligomers produced in the reactor such as dimers and trimers, iert materials such as nitrogen and, finally, oxygen which is a catalyst poison and must be removed or at least essentially removed.
SUMMARY OF THE INVENTION
It is an object of this invention to provide a process and apparatus for polymer recovery and recycle of diluent wherein monomer-free diluent is available for preparation of catalyst mud;
It is a further object of this invention to simplify the apparatus and process steps necessary for polymer recovery and diluent recycle in a slurry olefin polymerization process; and
It is yet a further object of this invention to avoid unnecessary separation of monomer from the diluent which is recycled directly back to the reactor.
It is still yet a further object of this invention to reduce the amount of vapor compression required.
In accordance with this invention, effluent from a polymerization zone is separated into a polymer stream and a diluent stream; thereafter a slip stream is taken off the diluent stream, subjected to monomer removal, and passed to a catalyst mixing zone, the remaining portion of the diluent stream being recycled to the polymerization zone.
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Burns David H.
Hottovy John D.
Kufeld Scott E.
Roetman Timothy
Vaidyanathan Ragavan
Owen Polly C.
Phillips Petroleum Company
Rabago R.
Wu David W.
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