Difunctional products from ethylene oxide and synthesis gas

Details Difunctional products from ethylene oxide and synthesis gas Difunctional products from ethylene oxide and synthesis gas

1989-06-29

1990-11-27

Killos, Paul J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

568428, 568429, C07C 6966

Patent

active

049737414

ABSTRACT:
A process for producing a .beta.-hydroxyester product or a .beta.-hydroxyaldehyde product from ethylene oxide, carbon monoxide, and, optionally, hydrogen, is disclosed. This process uses, as a catalyst, a catalyst comprising rhodium, ruthenium, and a Group Va promoter.

REFERENCES:
patent: 3687981 (1972-08-01), Lawerence et al.
H. C. Brown and K. A. Keblys, Journal of Organic Chemistry, 1966, vol. 31, p. 485.
R. S. Dickson, Homogeneous Catalysis with Compounds of Rhodium and Iridium, 1985.
J. L. Eisenmann, R. L. Yamartino, and J. F. Howard, Jr. Journal of Organic Chemistry, 1961, vol. 26 p. 2,102.
"Organic Synthesis via Metal Carbonyls", vol. 1, pp. 384-388, edited by Wender and Pino (John Wiley & Sons, Incorporated; 1968).
"Carbon Monoxide in Organic Synthesis", by J. Falbe, pp. 58-59 (Springer-Verlag, New York; 1970).
"Homogeneous Catalysis with Compounds of Rhodium and Iridium", by R. S. Dickson, pp. 133-134 (D. Reidel Publishing Company, Holland; 1985).
"New Synthesis with Carbon Monoxide", pp. 293-294 and 422-423 (Springer-Verlag, New York; 1980).
"Organic Synthesis via Metal Carbonyls", vol. 2, pp. 20-26, edited by Wender and Pino (John Wiley & Sons, New York; 1977).

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