Difluoroketones from difluoroacylsilanes

Details Difluoroketones from difluoroacylsilanes Difluoroketones from difluoroacylsilanes

1990-10-01

1991-10-15

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568404, 568812, 568842, 568843, 556470, C07C 4542

Patent

active

050576267

ABSTRACT:
A process for the synthesis of alpha,alpha-difluoroketones from alpha,alpha-difluoroacylsilanes and intermediates therefor.

REFERENCES:
patent: 4772714 (1988-09-01), Tanaka et al.
Metcalf et al., Tet. Letters 26, 2861-2864 (1985).
Yuan et al., J. Am. Chem. Soc. 109, 8071-8081 (1987).
Gelb, M. H., J. Am. Chem. Soc. 108, 3146-3147 (1986).

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