Diffusion coated ethylene furnace tubes

Metal treatment – Process of modifying or maintaining internal physical... – Processes of coating utilizing a reactive composition which...

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427205, C23C 2270, B05D 136

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active

058739513

ABSTRACT:
The inner surface of ethylene furnace tubes is diffusion coated with a sufficient amount of chromium or chromium and silicon to form a first coating having a thickness of at least two mils. This coating is then cleaned, neutralized, and grit blasted. Then a second coating of a sufficient amount of aluminum or aluminum and silicon is diffused onto the first coating to form a total coating thickness of at least five mils. The surface of the second coating is cleaned and polished to remove the nickel and iron-rich overlay which is present as a result of the coating process and to provide a smooth uniform surface. When ethelyene is produced using furnace tubes which are coated in this manner less coking occurs.

REFERENCES:
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patent: 4904301 (1990-02-01), Davis
patent: 5135777 (1992-08-01), Davis et al.
Patent Abstract of Japan, vol. 012, No. 015 (C-469), Jan. 16, 1988, of Japanese Patent Application No. 61013372, published Jul. 27, 1987.
Reprint from Oil & Gas Journal, "Aluminized ethylene furnace tubes extend operating life," Reprinted from the Aug. 31, 1987 edition of Oil & Gas Journal, Copyright 1987 by PennWell Publishing Company.
"A Study Of The Results Of 31/2 Years of Exposure Of Alonzied Tubes In An Ethylene Pyprolysis Furnace," Nov., 1984.
"Use alloys to improve ethylene proudction," Hydrocarbon Processing, Mar., 1996, pp. 53-61.
"Update in Alloy Selection for Ethylene Furnaces" by Steanson B. Parks and C. M. Schillmoller, A.I.Ch.E Spring Meeting, Mar. 19-23, 1995.

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