Diene-bis-aquo-rhodium(I) complexes, process for preparing...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

Reexamination Certificate

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C502S152000, C502S155000

Reexamination Certificate

active

10570018

ABSTRACT:
Diene-bis-aquo-rhodium(I) complex of the general formula [Rh(diene)(H2O)2]X where diene is a cyclic diene and X is a noncoordinating anion.

REFERENCES:
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patent: WO 02/36261 (2002-05-01), None
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Bergbreiter, David E. et al., “Amphoteric, Water-Soluble Polymer-Bound Hydrogenation Catalysts,” Tetrahedron Letters, 1997, pp. 3703-3706, vol. 38, No. 21, Elsevier Science Ltd., Great Britain.
Thewissen, D. Harry M. W. et al., “Synthese of α,ω-Bis(disphenylphosphino)alkane and α,ω-Bis(disphenylphosphino)-(poly)ether Ligands and Complexes of Rhodium(I),” Inorganica Chimica Acta, 1985, pp. 143-150, No. 97, Elsevier Sequioa, Switzerland.
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Hashmi, A. Stephen K. et al., “On the Enantioselective Rhodium-Catalyzed Enyne Cyclization,” Adv. Synth. Catal., 2003, pp. 1237-1241, No. 345, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany.
Case, Brenda L. et al., “Reusable, Recoverable, Polymeric Supports: Applications in Homogeneous Catalysis,” Chemical Industries, 1998, pp. 403-414, Issue 75, New York, NY.
Motoda, Dai et al., “Phosphane-Free Rhodium Catalyst in an Anionic Micellar System for [4+2] Annulation of Dienynes,” Angew. Chem., 2004, pp. 1896-1898, No. 116, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany.

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