Chemistry: electrical and wave energy – Apparatus – Electrolytic
Reexamination Certificate
1999-07-23
2001-12-11
Gorgos, Kathryn (Department: 1741)
Chemistry: electrical and wave energy
Apparatus
Electrolytic
C204S252000, C204S279000
Reexamination Certificate
active
06328860
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of Invention
The invention relates to electrolytic cells, particularly high amperage diaphragm electrolytic cells. The cells, typically chlor-alkali diaphragm cells, may operate at current capacities of upwards of about 200,000 amperes.
2. Description of the Related Art
It has been known to construct such cells where cathode outer sidewalls, made of electrically conductive material, are encircled with buss structure. For example, there has been shown in U.S. Pat. No. 3,390,072, a high amperage electrolytic cell wherein the sidewall is connected to a source of electrical current through an encircling bar-type bus member, sometimes referred to as a gird bar.
There has thereafter been developed busbar assemblies for diaphragm-type electrolytic cells wherein busbars are connected only to the cathode sidewall and have angled edges. For example, in U.S. Pat. No. 3,783,122, there are shown busbars of triangular shape, which busbars are shorter than the sidewall. Further in the development of angled busbars, several busbar strips, some of which can have triangular-shaped faces, may be utilized. This has been shown in U.S. Pat. No. 3,904,504, wherein it is disclosed to have a cathode busbar structure comprising several busbar strips. The numerous busbar strips, having different relative dimension, are welded to the sidewall.
With regard to fastening busbars to the sidewall, a combination of fastening means may be utilized. Generally, welding can provide for desirable electrical contact between the sidewall and a busbar. However, it is known to bolt a busbar to the sidewall, then weld the busbar at its edges to the sidewall. Bolting can assist in positioning of the busbar on the sidewall, then welding can assure desirable electrical contact as well as assisting in maintaining busbar positioning.
A more recent innovation for providing electrical current to electrolytic cells has improved the gird bar structure for distributing electrical current to the cathode sidewall. Thus as shown in U.S. Pat. No. 4,834,859, a gird bar is provided on a sidewall. In the structure of the innovation of this patent, distributor bars are placed on the inside of the sidewall at the upper and lower regions of the gird bar. These distributor bars conduct electrical current from the sidewall to an exterior face of an inner tube sheet. Cathode tubes are then positioned at the interior face of the tube sheet.
More recently, it has been proposed to provide a wall-sized busbar for the cathode sidewall. Such a structure is shown in U.S. Pat. No. 5,137,612. This patent discloses such a wall-sized busbar and the busbar is interface bonded to the cathode sidewall. The wall-sized busbar can have an extension section for attaching jumper switches.
It would nevertheless be desirable to provide a busbar structure for a cathode sidewall having not only efficient current distribution, but also reduced potential for sidewall stress corrosion cracking. It would also be desirable if such structure could provide reduced cathode manufacturing cost as well as accommodate stress relief characteristic.
SUMMARY OF THE INVENTION
It has now been found possible to provide an efficient cathode sidewall busbar structure having reduced potential for sidewall stress corrosion cracking. The structure of the innovation can further include a cathode sidewall assembly having reduced cathode electrical resistance, i.e., reduced structure drop during electrolytic cell operation. Other features of the present invention pertain to reduced cathode manufacturing cost as well as accommodation of stress relief for the cathode weldment.
In one aspect, the invention relates to an electrolytic cell wherein the cell comprises a walled enclosure providing at least one cathode sidewall for the enclosure and with there being cathode busbar structure external to the cell for conducting electrical current from the cathode sidewall to outside the cell through an outer gird bar extending along an outside face of the cathode sidewall. Within this framework, the invention of this aspect provides the improvement in busbar structure comprising:
a solid and elongated outer gird bar member releasably secured at the sidewall outside face; and
a small, solid cathode busbar member situated on the sidewall at least substantially adjacent to said gird bar member, which small busbar member is releasably secured to the sidewall outside face and is directly in contact with the sidewall.
In another aspect, the invention relates to an electrolytic cell wherein the cell comprises a walled enclosure providing at least one cathode sidewall for the enclosure and with there being cathode busbar means external to the cell, including an outer gird bar extending along an outside face of the cathode sidewall, and interior cell structure at an inside face of the cathode sidewall and including cell cathodes incorporating internal support members. Within this framework, the invention of this aspect provides the improvement in such structure comprising:
a solid and elongated outer gird bar member releasably secured at the sidewall outside face; and
internal support members supporting the cathodes situated within the electrolytic cell, with the internal support members being directly secured to the sidewall inside face.
A still further aspect of the invention pertains to interconnected electrolytic cells wherein each cell comprises a walled enclosure providing at least one cathode sidewall for said enclosure and electrical intercell connector means are present between adjacent cells, with interior cell structure including cell cathodes incorporating internal cathode support members. In this still further aspect, the improvement in such structure comprises:
an intercell connector means which is connected directly to an outside face of the cathode sidewall; and
interior cell structure directly secured to an inside face of the cathode sidewall.
Still other benefits and advantages of the invention will become apparent to those skilled in the art to which it pertains upon a reading and understanding of the following detailed specification.
REFERENCES:
patent: 4178225 (1979-12-01), Ruthel et al.
patent: 5137612 (1992-08-01), Romine et al.
patent: 5306410 (1994-04-01), Farmer
patent: 6045668 (2000-04-01), Fort et al.
patent: 6093442 (2000-07-01), Fort et al.
patent: 0 466 156 (1991-07-01), None
patent: 0 899 360 (1998-08-01), None
Manufacture Specifications of the Diaphragm cell with Metal Anodes, Sep. 1985, Author unknown.
Florkiewicz Thomas F.
Jahn John J.
Pohto Gerald R.
Romine Richard L.
Eltech Systems Corporation
Gorgos Kathryn
Hudak & Shunk Co. LPA
Nicolas Wesley A.
Tyrpak Michele M.
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