Diamines and polyimides containing pendent ethynyl groups

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564335, 528353, C07C21154, C07C21156

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active

053449827

ABSTRACT:
Diamines containing pendent ethynyl and substituted ethynyl groups are synthesized. These diamines are reacted with dianhydrides to form polyamide acids, which are chemically or thermally cyclodehydrated to form polyimides and copolyimides with pendent ethynyl groups. Upon heating, the pendent ethynyl groups react to form crosslinked resins that are useful as adhesives, composite matrices, coatings, moldings and films.

REFERENCES:
patent: 3828071 (1974-08-01), Kast et al.
patent: 4990667 (1991-02-01), Burgoyne et al.
Jensen et al, Chemical Abstracts, vol. 118 (1993) 213671m.

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