Diacyl peroxy compounds

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260 2EP, 260 13, 260 75T, 260463, 260453R, 260475P, 260476C, 260485C, 260485P, 260544L, 260544B, 260544R, 260545R, 260546, 260879, 260880R, 260881, 260884, 260885, 260886, 260934, 526 7, 526335, 526340, 526346, 526347, C07C 5932, C07C 6136, C07C 6520

Patent

active

039911098

ABSTRACT:
I. A novel class of compounds X.sub.n --R.sub.p --Y.sub.m where R is a 2-4 valence aliphatic, cycloaliphatic or aromatic radical, X is an acylating function; Y is a peroxy containing group and n and m are each equal to 1-2 and p is at least 1.
Ii. a novel class of polymers [A.sub.n -(R-D.sub.n).sub.n ].sub.v -P.sub.w -Z where A is a peroxy containing group; R is a 2-4 valence aliphatic, cycloaliphatic or aromatic radical, P is a polyvalent polymeric residue; D is a carbonyl containing connecting group; Z is H, OH, NH.sub.2, NHR.sub.2, SH or R.sub.2 O group; v and w are each equal to 1-100; and n is equal to 1-2.
Iii. polymers II are useful with vinyl monomers in the formation of block and graft polymers.
Iv. peroxides having an acylating function are prepared by reacting at 0.degree.-80.degree. C an organic peroxide having an hydroxyl or carboxyl group with a defined acylating reactant.
V. peroxides having at least one acylating function are prepared by peroxidizing a compound having at least two acylating functions as the only peroxidizable substituents.

REFERENCES:
patent: 2978495 (1961-04-01), Frankel et al.
patent: 3165546 (1965-01-01), Merrill
patent: 3288855 (1966-11-01), Schisla et al.
patent: 3632630 (1972-01-01), Chao et al.
patent: 3646108 (1972-02-01), Jones et al.

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