Di-ortho-substituted di-meta-halogenated para-halomethylphenols

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568779, C07C 3924

Patent

active

047406364

ABSTRACT:
Included is a process to prepare a 4-HALOmethyl-3,5-dihalo-2,6-disubstitutedphenol from a 4-methyl(substituted)phenol and a HALOgenating agent, in an aprotic organic diluent. The process is highly selective and efficient. For example, high purity 4-bromomethyl-3,5-dibromo-2,6-dimethylphenol can be prepared from 2,4,6-trimethylphenol and bromine, in bromochloromethane at high conversion.

REFERENCES:
patent: 4328361 (1982-05-01), Dai
patent: 4684752 (1987-09-01), Mendoza

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