Devices comprising PTC conductive polymers

Adhesive bonding and miscellaneous chemical manufacture – Methods – Surface bonding and/or assembly therefor

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156 86, 174DIG8, 219200, 219535, 219541, 219547, 219548, 219549, 338212, 338214, B32B 3126

Patent

active

047433213

ABSTRACT:
The resistivity/temperature characteristics of PTC conductive polymers which have little or no cross-linking can be modified by stretching. The rate at which resistivity rises with temperature is increased, and the peak resistivity is decreased; however, the decrease in peak resistivity is substantially smaller than that observed with PTC conductive polymers having a high degree of cross-linking. Therefore, heat-recoverable electrical devices, particularly for covering telephone and other cable splices, comprise (a) a layer of a PTC conductive polymer which has little or no cross-linking, (2) an adjacent heat-recoverable layer of a PTC or ZTC conductive polymer which has a relatively high level of cross-linking, and (3) electrodes which can be connected to a power supply so that current passes through the layers and causes recovery of the device; preferably an uncrosslinked PTC layer is sandwiched between two cross-linked ZTC layers. Non-recoverable devices, e.g. heaters, can have valuable characteristics when they comprise PTC conductive polymer elements which have been given a relatively low degree of orientation by stretching.

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