Devices and methods for generating electrogenerated chemilumines

Details Devices and methods for generating electrogenerated chemilumines Devices and methods for generating electrogenerated chemilumines

1992-02-11

1994-06-28

Tucker, Philip

Compositions

Chemiluminescent

362 34, 25230133, 25230136, 252583, C09K 300, C09K 1106, C09K 1102, F21K 200

Patent

active

053244575

ABSTRACT:
Devices and methods for generating electrogenerated chemiluminescence, using an electrode which is coated with an immobilized layer of a compound capable of generating ECL. The coated electrode can be immersed along with a second electrode into an electrolyte solution containing a reactant which can react with the immobilized compound to generate ECL.

REFERENCES:
patent: 3503893 (1970-03-01), Hercules et al.
patent: 4054368 (1977-10-01), Krueger et al.
patent: 5075172 (1991-12-01), Dixon et al.
Zhang, et al., "Electrogenerated Chemiluminescent Emission from an Organized (L-B) Monolayer of a Ru(bpy).sub.3.sup.2+ -Based Surfactant on Semiconductor and Metal Electrodes", J. Phys. Chem., vol. 92, No. 20, pp. 5566-5569 (1988).
Kalyanasundaram, "Photophysics, Photochemistry and Solar Energy Conversion With Tris (Bipyridyl)Ruthenium (II) and Its Analogues", Coordination Chemistry Reviews, vol. 46, pp. 159-244 (1982).
Daifuku, et al., "Electrode Kinetics of Surfactant Polypyridine Osmium and Ruthenium Complexes Confined to Tin Oxide Electrodes in a Monomolecular Layer by the Langmuir-Blodgett Method", J. Electroanal. Chem., vol. 183, pp. 1-26 (1985).
Lee, et al., "Comparative Electrochemical Studies of N-Methyl-N'-Hexadecyl Viologen Monomolecular Films Formed by Irreversible Adsorption and the Langmuir-Blodgett Method", J. Electroanal. Chem., vol. 239, pp. 441-446 (1988).
Fujihira, et al., "Electrochemistry of the Redox-Active Langmuir-Blodgett Films Coated on Glassy Carbon Electrodes", Bull. Chem. Soc. Jpn., vol. 59, pp. 2375-2379 (1986).
Facci, et al., "Characterization of Electroactive Langmuir-Blodgett Monolayers of (Ferrocenylmethyl)dimethyloctadecyl-ammonium Sulfate at Gold and Air/Water Interfaces", Langmuir, vol. 2, No. 6, pp. 732-738 (1986).
Yokota, et al., "Redox Behavior of Cytochrome c Immobilized Into a Lecithin Monolayer and Deposited onto SnO.sub.2 by the Langmuir-Blodgett Technique", J. Electroanal. Chem., vol. 216, pp. 289-292 (1987).
Matsuda, et al., "Theory of Electrode Reactions of Redox Couples Confined to Electrode Surfaces at Monolayer Levels, Part I, Expression of the Current-Potential Relationship for Simple Redox Reactions", J. Electroanal. Chem., vol. 217, pp. 1-13 (1987).
Rubinstein, et al., "Polymer Films on Electrodes. 4. Nafion-Coated Electrodes and Electrogenerated Chemiluminescence of Surface-Attached Ru(bpy).sub.3.sup.2+ ", J. Am. Chem. Soc., vol. 102, pp. 6641-6642 (1980).
Rubinstein, et al., "Polymer Films on Electrodes. 5. Electrochemistry and Chemiluminescence at Nafion-Coated Electrodes", J. Am. Chem. Soc., vol. 103, pp. 5007-5013 (1981).
Abruna, et al., "Electrogenerated Chemiluminescence. 40. A Chemiluminescent Polymer Based on the Tris(4-vinyl-4'-methyl-2,2'-bipyridyl)ruthenium(II) System", J. Am. Chem. Soc., vol. 104, 2641-2642 (1982).
Brilmyer, et al., "Electrogenerated Chemiluminescence. XXXVI. The Production of Steady Direct Current ECL in Thin Layer and Flow Cells", J. Electrochem. Soc., vol. 127, No. 1, pp. 104-110 (1980).
Lee, et al., "Electrogenerated Chemiluminescence. Part 51. The Tris(2,2'-Bipyrazine)Osmium(II) System", J. Electroanal. Chem., vol. 244, pp. 319-324 (1988).
Ouyang, et al., "Electrogenerated Chemiluminescence, 50. Electrochemistry and Electrogenerated Chemiluminescence of Micelle Solubilized OS(bpy).sub.3.sup.2+ ", Bull. Chem. Soc. Jpn., vol. 61, No. 1, pp. 17-24 (1988).
Ege, et al., "Electrogenerated Chemiluminescent Determination of Ru(bpy).sub.3.sup.2+ at Low Levels", Analytical Chemistry, vol. 56, No. 13, pp. 2413-2417 (1984).
Rubinstein, et al., "Electrogenerated Chemiluminescent Determination of Oxalate", Analytical Chemistry, vol. 55, No. 9, pp. 1580-1582 (1983).

Affiliated with

Also associated with

Rating

Devices and methods for generating electrogenerated chemilumines does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Devices and methods for generating electrogenerated chemilumines, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Devices and methods for generating electrogenerated chemilumines will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-2375994