Device with π-conjugated metal complex immobilized...

Details Device with π-conjugated metal complex immobilized... Device with π-conjugated metal complex immobilized...

2011-06-21

2011-06-21

Bell, Bruce F (Department: 1759)

Chemistry: electrical and wave energy

Apparatus

Electrolytic

Reexamination Certificate

active

07964071

ABSTRACT:
A π-conjugated metal complex immobilized substrate, in which π-conjugated metal complex molecules are connected to a substrate via a π-conjugated molecular structure, is adapted for observing an electron transfer (redox reaction) of the π-conjugated metal complex molecules in aqueous electrolytes. An electrochemical device including this π-conjugated metal complex immobilized substrate and an aqueous electrolyte with cations having an ion radius of r (m) that is not less than a radius of a sphere inscribed in a clearance formed between the π-conjugated metal complex molecules. The device utilizes an electron transfer (redox reaction) of the π-conjugated metal complex molecules in the aqueous electrolyte.

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Katsuhiko Kanaizuka et al., “Stepwise Preparation of Linear π-Conjugated Bis(terpyridine)metal Polymer Chains at Gold Surface,” 34(4) Chemistry Letters 534-35 (Mar. 2005).

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