Device with n-type semiconductor

Active solid-state devices (e.g. – transistors – solid-state diode – Organic semiconductor material

Reexamination Certificate

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C257S040000, C257S759000

Reexamination Certificate

active

06861664

ABSTRACT:
An electronic device includes a semiconductor layer in contact with a number of electrodes, wherein the semiconductive layer includes a compound wherein either or both of the following geometric isomers of the compound are present:wherein:n is 1, 2 or 3 for the polycyclic moiety; andR1and R2are independently selected from the group consisting of a hydrocarbon ring and a heterocyclic group, wherein R1and R2are the same or different hydrocarbon ring, the same or different heterocyclic group, or one of R1and R2is the hydrocarbon ring and the other the heterocyclic group.

REFERENCES:
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patent: 5174921 (1992-12-01), Buchecker et al.
patent: 5225307 (1993-07-01), Hor et al.
patent: 6387727 (2002-05-01), Katz et al.
patent: 20020164835 (2002-11-01), Dimitrakopoulos et al.
Amit Babel et al., “Electron Transport in Thin-Film Transistors from an n-Type Conjugated Polymer,”Adv. Mater.14, No. 5, pp. 371-374 (Mar. 4, 2002).
H.E. Katz et al., “A soluble and air-stable organic semiconductor with high electron mobility,”Nature, vol. 404, pp. 478-480 (Mar. 30, 2000).
Patrick R. L. Malenfant et al., “N-type organic thin-film transistor with high field-effect mobility based on a N,N'-dialkyl-3,4,9,10-perylene tetracarboxylic diimide derivative,”Applied Physics Letters, vol. 80, No. 14, pp. 2517-2519 (Apr. 8, 2002).
Howard E. Katz et al., “Naphthalenetetracarboxylic Diimide-Based n-Channel Transistor Semiconductors: Structural Variation and Thiol-Enhanced Gold Contacts,”J. Am. Chem. Soc.,vol. 122, pp. 7787-7792 (2000).
J. H. Schon et al., “Perylene: A promising organic field-effect transistor material,”Applied Physics Letters, vol. 77, No. 23, pp. 3776-3778 (Dec. 4, 2000).

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