Device for the generation of hydrogen

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

Reexamination Certificate

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C502S304000, C502S332000, C502S344000, C502S349000, C502S350000, C422S141000, C422S142000, C422S146000, C422S149000, C422S187000, C422S186220, C422S186220, C422S198000, C422S198000, C422S198000, C422S199000, C422S200000, C422S202000

Reexamination Certificate

active

07632778

ABSTRACT:
An apparatus for producing hydrogen, which comprises:a. a heated steam reforming stage (1) with a reforming catalyst to convert gaseous or vaporizable hydrocarbons and water into hydrogen, carbon monoxide and further reformer products;b. at least one stage downstream of the steam reforming stage for the catalytic conversion of the mixture of hydrogen, carbon monoxide and excess steam leaving the steam reforming stage (shift stage) (2); andc. a fine purification stage (3) downstream of the shift stage(s) for the catalytic lowering of the residual carbon monoxide content of the conversion products by selective methanization,is described.In the apparatus, the shift stage (2) and the fine purification stage (3) are configured as a unitary hollow body (exothermic catalyst stage).

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Bunluesin, T., et al., Studies of the water-gas-shift reaction on ceria-supported Pt, Pd, and Rh: implications for oxygen-storage properties, Applied Catalysis B: Environmental 15, 1998, pp. 107-114.

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