Deuterium separation by infrared-induced addition reaction

Details Deuterium separation by infrared-induced addition reaction Deuterium separation by infrared-induced addition reaction

1976-05-28

1977-05-24

Schafer, Richard E.

Chemistry: electrical and wave energy

Processes and products

Electrostatic field or electrical discharge

423648A, 250284, 250423P, 204DIG11, B01J 110, B01D 5934

Patent

active

040254089

ABSTRACT:
A method for deuterium enrichment by the infrared-induced addition reaction of a deuterium halide with an unsaturated aliphatic compound. A gaseous mixture of a hydrogen halide feedstock and an unsaturated aliphatic compound, particularly an olefin, is irradiated to selectively vibrationally excite the deuterium halide contained therein. The excited deuterium halide preferentially reacts with the unsaturated aliphatic compound to produce a deuterated addition product which is removed from the reaction mixture.

REFERENCES:
Chemical Physics Letters 1975, 34(1), pp. 84-89.
Soviet Atomic Energy 1973, 33(4), p. 961.

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