Determination of chlorate ion concentration using microelectrode

Electrolysis: processes – compositions used therein – and methods – Electrolytic analysis or testing – For halogen or halogen containing compound

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204400, 204412, 205780, G01N 2726

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active

059482362

ABSTRACT:
An in-situ procedure is described for measuring chlorate ion concentration in aqueous media containing the same by employing electrodes, particularly microelectrodes which generate a sigmoidal-type response at high chlorate ion concentration, and which exhibit catalytic properties toward chlorate ion electroreduction or electrooxidation.

REFERENCES:
patent: 4028197 (1977-06-01), Capuano
patent: 5437772 (1995-08-01), De Castro et al.
Gifford et al, "Pneumatoamperometric Determination of Parts-per-Billion Dissolved Speries by Evoling Reactions", Analyticals Chemistry, vol. 25, No. 7, Jun. (1980), pp. 1024-1028.
Vogel's "Textbook of Quantitative Inorganic Analysis" Fourth edition 1978 month unavailable, pp. 363, 381, 493, 494.
"The Behavior of Microelectrodes" by S. Pons and M. Fleischmann, Analytical Chemistry, vol. 59, No. 24 (Dec. 15, 1987), pp. 1391A-1399A.

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