Determination of actinides in urine and fecal samples

Chemistry: analytical and immunological testing – Metal or metal containing – Zn – cd – hg – sc – y – or actinides – or lanthanides

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436 57, 436 74, 436 81, 436175, 436177, 422 681, G01N 3320

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active

051908816

ABSTRACT:
A method of determining the radioactivity of specific actinides that are carried in urine or fecal sample material is disclosed. The samples are ashed in a muffle furnace, dissolved in an acid, and then treated in a series of steps of reduction, oxidation, dissolution, and precipitation, including a unique step of passing a solution through a chloride form anion exchange resin for separation of uranium and plutonium from americium.

REFERENCES:
patent: 4835107 (1989-05-01), Horowitz et al.
Holm et al. Talanta, vol. 23, pp. 853-855, 1976. "Determination of Americum and Curium by Using ion-exchange in Nitric acid-methanol medium for environmental analysis".
Kressin, Analytical Chemistry, vol. 53, 1981, pp. 1270-1274. "Separation of Plutonium in Urine without Sample Ashing for Determination by .alpha.-Spectrometry".
Hindman Analytical Chemistry, vol. 55, 1983, pp. 2460-2461. "Neodymium Fluoride Mounting for .alpha. Spectrometric Determination of Uranium, Plutonium, and Americium".
Hindman, Analytical Chemistry, vol. 58, 1986, pp. 1238-1241. "Actinide Separations for .alpha.-Spectrometry Using Neodymium Fluoride Coprecipitation".

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