Detergent alkylation using a regenerable clay catalyst

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...

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502 20, 502 31, 585446, C07C 266

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active

054912717

ABSTRACT:
Tetrahedrally charged clays have been found to be active, regenerable catalysts in detergent alkylation, both as delaminated and pillared clays. The pillared saponites and beidellites are especially favored in forming detergent range alkylates using olefins as the alkylating agent to afford products with high monoalkylation selectivity and high linearity. Catalysts can be regenerated by a benzene wash or, after severe deactivation, by a carbon burn.

REFERENCES:
patent: 5034564 (1991-07-01), Kocal
patent: 5118897 (1992-06-01), Khonsari et al.
patent: 5358915 (1994-10-01), Nebergall et al.

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