Cleaning compositions for solid surfaces – auxiliary compositions – Cleaning compositions or processes of preparing – Specific organic component
Reexamination Certificate
2000-09-22
2003-01-14
Hardee, John (Department: 1751)
Cleaning compositions for solid surfaces, auxiliary compositions
Cleaning compositions or processes of preparing
Specific organic component
C564S396000
Reexamination Certificate
active
06506721
ABSTRACT:
This invention relates to a novel composition useful as a detergent additive and processes for making and using such composition.
BACKGROUND OF THE INVENTION
Commercial and household detergent compounds are well known. Improved detergents are constantly being developed to provide less expensive, more environmentally friendly, and more effective cleaning products.
The effectiveness of a detergent can be measured in many different ways. The most obvious measure of a detergent's effectiveness is its ability to remove undesirable compounds from a base material without negatively impacting the properties of the base material; however, depending on the function for which a specific detergent is intended, its effectiveness is measured in other ways. The effectiveness of laundry detergent, for example, can be measured by its ability to dissolve in water, minimize suds, prevent calcium build-up, soften fabrics, and clean multiple fabrics.
New detergent additives are frequently mixed with existing detergents or substituted for less desirable detergent components in order to decrease cost, increase effectiveness, and produce more environmentally friendly detergents.
It is therefore an object of the present invention to provide a novel composition which, when admixed with a detergent, will create an economically feasible, environmentally friendly, and/or more effective detergent.
It is further an object of the present invention to provide methods for making and using such novel composition.
Other objects and advantages of the present invention will become apparent from the description, the example, and the appended claims.
SUMMARY OF THE INVENTION
In a first embodiment of the present invention a novel composition is provided. The novel composition has the following formula:
wherein R
1
is selected from the group consisting of an alkyl group containing from 1 to 20 carbon atoms and an aryl group; and R
2
is selected from the group consisting of an alkyl group containing from 1 to 20 carbon atoms and an aryl group.
In a second embodiment of the present invention a process of making the above-described novel composition is provided. The process comprises the following steps: (a) combining an amine compound, a carbonyl compound, and a solvent compound to produce a first product; (b) combining the first product and a sulfur-containing compound to produce a second product; and, (c) separating the second product to obtain a substantially pure quantity of the novel composition described in the first embodiment of the present invention.
In a third embodiment of the present invention a process of using the above-described novel composition is provided. The process comprises the following steps: (a) admixing the novel composition described in the first embodiment of the present invention with a detergent composition to produce a modified detergent composition; and, (b) contacting the modified detergent composition with an undesirable compound attached to a base material.
DETAILED DESCRIPTION OF THE INVENTION
According to a first embodiment of the present invention, a novel composition useful as a detergent additive has been discovered. The novel composition comprises, consists of, or consists essentially of, a composition having the following formula:
wherein R
1
is selected from the group consisting of an alkyl group containing from 1 to 20 carbon atoms and an aryl group; and R
2
is selected from the group consisting of an alkyl group containing from 1 to 20 carbon atoms and an aryl group. Preferred aryl groups include a phenyl group and a substituted phenyl group including a phenyl substituted with both a hydroxy and a methyl. Preferred alkyl groups include alkyl groups containing from 1 to 6 carbon atoms. More preferred alkyl groups include the substituents of ethyl, methyl, propyl, butyl, 2-hydroxy ethyl, and 3-hydroxy propyl. Even more preferably each of R
1
and R
2
is an ethyl group. Most preferably the novel composition is diethylaminomethyl 2-hydroxyethylsulfide.
According to a second embodiment of the present invention, a process for making the novel composition described in the first embodiment of the present invention has been discovered. Such process of making comprises the following steps: (a) combining under reaction conditions an amine compound, a carbonyl compound, and a solvent compound to produce a first product; (b) combining under reaction conditions the first product and a sulfur-containing compound to produce a second product; and, (c) separating the second product to obtain a substantially pure quantity of the novel composition described in the first embodiment of the present invention.
The amine compound employed in step (a) can be any amine compound capable of reacting with a carbonyl compound. Preferably the amine compound is a secondary amine compound. More preferably the amine compound is a compound selected from the group consisting of diethylamine, dimethylamine, diethanolamine, N-ethylmethylamine, dipropylamine, diisopropylamine, dibutylamine, diphenylamine, dibenzylamine, dialkylamine, and diisobutylamine. Most preferably the amine compound is diethylamine.
The carbonyl compound employed in step (a) can be any carbonyl compound capable of reacting with an amine. Preferably the carbonyl compound is aldehyde or a ketone. More preferably the carbonyl compound is an aldehyde compound selected from the group consisting of formaldehyde and paraformaldehyde. Most preferably the carbonyl compound is paraformaldehyde.
The solvent compound employed in step (a) can be any solvent compound capable of dissolving the amine compound and the carbonyl compound. Preferably the solvent compound is an aromatic hydrocarbon capable of forming an azeotrope with water. More preferably the solvent compound is a compound selected from the group consisting of toluene, benzene, and xylenes. Most preferably the solvent compound is toluene.
The first product, produced in step (a), can be any composition or mixture of compositions produced by combining the amine compound, the carbonyl compound, and the solvent compound and capable of reacting with a sulfur-containing compound. The first product can comprise unreacted reactants, water, products from the reaction of the amine compound and the carbonyl compound, and products from side reactions.
The individual quantities of the amine compound, the carbonyl compound, and the solvent compound combined in step (a) can be any quantities effective to produce the first product. Preferably the quantities of the compounds employed in step (a) provide a molar ratio of the amine compound to the carbonyl compound of from about 10:1 to about 1:10, preferably from about 5:1 to about 1:2, and most preferably from 1.3:1 to 1:1.3. Preferably the molar ratio of the solvent compound to the carbonyl compound is less than about 100:1, more preferably less than about 10:1, even more preferably less than about 5:1, and most preferably less than 1:1.
The amine compound, the carbonyl compound, and the solvent compound may be combined in step (a) under reaction conditions sufficient to produce the first product. Preferably the reaction conditions include a temperature in the range of from about 0° C. to about 300° C., more preferably from about 5° C. to about 250° C., and most preferably from 10° C. to 200° C.; and a pressure in the range of from or about below atmospheric to or about 5 atmospheres, more preferably from about atmospheric to about 3 atmospheres, and most preferably from atmospheric to 2 atmospheres.
Between steps (a) and (b) it may be desirable to remove water from the first product. Water may be removed from the first product using any suitable method know in the art. Preferred methods of removing water from the first product include azeotropic distillation, absorption, and chemical reaction. Azeotropic distillation is presently the most preferred method of water removal.
The sulfur-containing compound employed in step (b) can be any mercaptan capable of reacting with the first product. Preferably the sulfur-containing compound is an alkyl merca
Dockter David W.
Refvik Mitchell D.
Hardee John
Phillips Petroleum Company
Stewart Charles W.
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