Desulfurization and hydroconversion of residua with alkaline ear

Mineral oils: processes and products – Chemical conversion of hydrocarbons – Cracking

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Details

208112, 208213, 208214, 208226, 252439, 252475, C10G 1304, B01J 2704

Patent

active

040873480

ABSTRACT:
Sulfur-containing petroleum oil feedstocks which include heavy hydrocarbon constituents undergo simultaneous desulfurization and hydroconversion by contacting such feedstocks with alkaline earth metal hydrides or alkaline earth metal oxides, particularly barium hydride or barium oxide, in the presence of hydrogen, and at elevated temperatures. The mixtures of reaction products resulting from the above procedure can be separated to give a petroleum oil product which has been substantially desulfurized and demetallized and significantly upgraded as demonstrated by reduced Conradson carbon content, and increased API gravity and which includes alkaline earth metal sulfide salts from which the alkaline earth metal hydrides or oxides may be regenerated.

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patent: 2886513 (1959-05-01), Baker
patent: 3663433 (1972-05-01), Fraini et al.
patent: 3715303 (1973-02-01), Wennerberg et al.
patent: 3787315 (1974-01-01), Bearden et al.
patent: 3846287 (1974-11-01), Jaffe et al.

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