Desulfurization and hydrocarbon quality enhancement process

Mineral oils: processes and products – Refining – Sulfur removal

Patent

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Details

208106, 208189, 208219, 208213, 208226, 208230, 208237, 423230, 585854, C10G 1700, C10G 1900, C01B 1716, C07C 700

Patent

active

058582126

ABSTRACT:
A hydrocarbon stream containing sulfur and sulfur compounds is contacted with a water suspension of dolomitic lime and dibasic acid catalyst in a reaction vessel in order to transfer the sulfur and sulfur compounds from the petroleum vapor to the water phase. During sulfur removal, naphthenic acid present in the hot petroleum vapor is converted to a high quality naphtha fraction. In the water phase, the sulfur compounds react with the available alkalinity from the dolomitic lime and dibasic acid. The insoluble calcium or magnesium based reaction products can then be removed from the water phase through conventional solids concentrating and separating equipment.

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