Desulfurization adsorbent for fuel cell and desulfurizing...

Catalyst – solid sorbent – or support therefor: product or process – Solid sorbent – Silicon containing

Reexamination Certificate

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C502S406000

Reexamination Certificate

active

07842645

ABSTRACT:
A desulfurization adsorbent for a fuel cell has a structure according to Formula 1 below, and a desulfurizing method uses the desulfurization adsorbent. The desulfurization adsorbent displays remarkably excellent adsorption performance for adsorbing sulfur compounds as well as excellent regeneration performance, compared with conventional desulfurization adsorbents. Thus, the desulfurization adsorbent does not need to be replaced even after prolonged use, thus stabilizing the operation of a fuel cell system and reducing costs.in-line-formulae description="In-line Formulae" end="lead"?(M1)a-(Si)x—(Ti)y-(M2)z-O  [Formula 1]in-line-formulae description="In-line Formulae" end="tail"?wherein M1is at least one selected from alkali metals, alkaline earth metals, hydrogen, ammonium, rare earths, and transition metals; 4≦x/y≦500, 0≦z/y≦3, 0≦a/(y+z)≦1; and M2is aluminum (Al), boron (B) or a trivalent metal. The desulfurization adsorbent is produced by subjecting a mixture of a silicon source, a titanium source, and optionally, aluminum, boron or a trivalent metal in an alkali solution to a hydrothermal treatment to obtain a crystalline porous molecular sieve.

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Chinese Office Action dated Apr. 8, 2010, issued in corresponding Chinese Patent Application No. 200610142810.6.

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