Explosive and thermic compositions or charges – Structure or arrangement of component or product
Patent
1992-02-24
1997-04-29
Jordan, Charles T.
Explosive and thermic compositions or charges
Structure or arrangement of component or product
149 36, 149 92, 1491096, C06B 4500, C06B 4708, C06B 2534
Patent
active
056251653
ABSTRACT:
Method is provided for reducing the sensitivity of energetic materials (explosives, propellants and the like) to detonation induced by mechanical shock or by application of pronounced heat, e.g. by a laser beam. Examples of such energetic materials are fluorine azide and chlorine azide which are model HEDM propellants which are prone to accidental detonation in the solid state. The polycrystalline forms of such solids are sensitive to and readily detonated by, mechanical shock and pulsed laser photolysis. The method of the invention serves to desensitize such energetic materials by forming them as amorphous (disordered) solids by vapor deposition thereof onto a relatively cold substrate, which amorphous form desensitizes them relative to more conventional polycrystalline forms of these energetic materials though both contain about the same amount of chemical energy.
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Kligmann Peter M.
Wight Charles A.
Chi Anthony R.
Jordan Charles T.
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