Derivatives of 5-hydroxy-6-diloweralkylaminomethyl-benzofurans

Details Derivatives of 5-hydroxy-6-diloweralkylaminomethyl-benzofurans Derivatives of 5-hydroxy-6-diloweralkylaminomethyl-benzofurans

1974-05-13

1976-09-28

Trousof, Natalie

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2602472B, 260268BC, 26029358, 26032634, 424285, 424248, 424250, 424274, C07D30784

Patent

active

039831418

ABSTRACT:
Derivatives of 5-oxy-6-aminomethylbenzofuran having the general formula ##SPC1##
Where R is alkyl, R' is alkyl, aryl, R.sup.2 is alkyl, R.sup.3 is alkyl, or R.sup.2 and R.sup.3, together with a nitrogen atom to which they are bonded, form a heterocycle comprising one or two hetero-atoms, and X is a halogen.
Said compounds are prepared by aminomethylation of derivatives of 5-oxybenzofuran having the formula ##SPC2##
Where R is alkyl, R' is alkyl, aryl, and X is a halogen.
The reaction of aminomethylation can be carried out with a substituted bisaminomethane or with a mixture, consisting of a secondary amine and formaldehyde.
Said compounds possess pharmacological activity.

REFERENCES:
grinev et al., Chem. Abstr., vol. 59 (1963), 7466a.
Kumar et al., Chem. Abstr., vol. 62 (1965), 11765e.

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