Derivatives and reduction products of D-glucopyranosyl-alpha(1.f

Details Derivatives and reduction products of D-glucopyranosyl-alpha(1.f Derivatives and reduction products of D-glucopyranosyl-alpha(1.f

1983-12-16

1986-10-21

Brown, Johnnie R.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carbohydrates or derivatives

536 41, 536124, C07H 1504

Patent

active

046186751

ABSTRACT:
The invention relates to derivatives and reduction products of D-glucopyranosyl-alpha(1.fwdarw.5)-d-arabinonic acid, having the general formula: ##STR1## wherein X is one of the following groups: --COOM, --COOR', CONH.sub.2 or --CH.sub.2 OH, where M is an alkali metal and R' is an alkyl group; and where R is a hydrogen atom or an acyl group. The compounds of formula (I) include compounds in which the arabinonic acid chain is closed in a lactone ring.
A method for producing the derivatives and reaction products is described, and uses therefor are also provided.

REFERENCES:
patent: 2190377 (1940-02-01), Dalmer et al.
patent: 3565885 (1968-10-01), Molotsky et al.
patent: 4117173 (1978-09-01), Schiweck et al.
patent: 4322523 (1982-03-01), Wagner
Stanek et al., The Monosaccharides, 1963, pp. 138-141.
Pigman, The Carbohydrates, 1957, p. 148.
Migrdichian, Organic Synthesis, vol. 1, 1957, pp. 9-10, 30, 162 and 311 & 322.
"The Monosaccharides", in Academic Press, New York, pp. 138ff., 1963.
Dubourg et al, "Oxidation des Hexoses Reducteurs par l'Oxygene en Milieu Alcalin", in Bull. Soc. Chim. Fr., pp. 1353ff., 1959.

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