Derivative of brendane and process for preparing the same

Details Derivative of brendane and process for preparing the same Derivative of brendane and process for preparing the same

1985-07-15

1987-04-07

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560114, 562497, 562499, C07C 69757, C07C 6112

Patent

active

046563075

ABSTRACT:
According to the invention a derivative of brendane is provided. The derivative of brendane is represented by the general formula of: ##STR1## wherein R is a hydrogen atom or a hydrocarbon group having 1 to 6 carbon atoms, and R.sup.1 to R.sup.3 each represent a hydrogen atom or a methyl group. The brendane derivative is prepared by reacting an alkenylnorbornene of the general formula of: ##STR2## wherein R.sup.1 to R.sup.3 each represent a hydrogen atom or a methyl group, with carbon monoxide and an alcohol or water in the presence of a catalyst of Group VIII metal compound of the periodic table.

REFERENCES:
Hirao et al., Tetrahedron Letters, 1976, pp. 3895-3898.
Hirao et al., Heterocycles, vol. 7, No. 2, 1977, pp. 857-862.

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