Deprotection of allylic esters, carbonates and carbamates cataly

Details Deprotection of allylic esters, carbonates and carbamates cataly Deprotection of allylic esters, carbonates and carbamates cataly

1979-01-10

1982-02-09

Rizzo, Nicholas S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260239A, 568830, 568885, 568884, 564458, 2602391, C07D50104, C07D49904

Patent

active

043149421

ABSTRACT:
An improved synthetic process for the removal of an allyl group in an allylic ester or an allyloxycarbonyl group in an allylic carbonate or carbamate by reaction with 2-ethylhexanoic acid or an alkali metal salt thereof and a catalytic amount of an organic-soluble palladium complex is disclosed herein.

REFERENCES:
Tetrahedron Letters 43 1970, pp. 3821-3824.
Chemical Communications 21 1970, pp. 1392-1393.
Atkins et al., Tetrahedron Letters 43 pp. 3821-3824, (1970).
Hata et al., Chemical Communications 21 pp. 1392-1393, (1970).
Jac S. 71 725 (1949.
J. Org. Chem. 38 3223 (1973).
Tsuji et al., Tetrahedron Letters 7 613-616 (1979).

Affiliated with

Also associated with

Rating

Deprotection of allylic esters, carbonates and carbamates cataly does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Deprotection of allylic esters, carbonates and carbamates cataly, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Deprotection of allylic esters, carbonates and carbamates cataly will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1260289