Depression of the glass transition temperature of polyolefins co

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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C08K 501

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059816430

ABSTRACT:
Copolymers of ethylene and a cyclic olefin, preferably a fused ring cyclic olefin (FRCO), optionally containing an alpha-olefin and/or a non-conjugated diene, display increasing glass transition temperatures (T.sub.g) as the amount of FRCO in the copolymer increases. This increase brings these polymers quickly above a T.sub.g acceptable as elastomers. Addition of specially selected process oils, based on cohesive energy densities of both the copolymer and the process oil, is shown to lower T.sub.g to a range acceptable for elastomers e.g. below about -30.degree. C. The copolymer/process oil combination can then be used in elastomer compounding operations and behave in typical elastomer fashion.

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