Depolymerization of condensation polymers involving a pre-molecu

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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562485, 562487, 562458, 562554, 562590, 562593, 564498, 568858, C07C 51487, C07C 9912, C07C 2726, C07C 8526

Patent

active

046200320

ABSTRACT:
There is disclosed a process for reducing the reaction time in the hydrolysis of a condensation polymer wherein molten condensation polymer is intimately admixed with a depolymerizing agent which is either (i) one of the products resulting from the complete hydrolytic depolymerization of the condensation polymer; or (ii) water. The depolymerization agent is present in the mixture in an amount which is less than the weight of the condensation polymer and the materials are intimately admixed for a time sufficient that the molecular of the condensation polymer is reduced by at least 50%. The treated condensation polymer of lower molecular weight is thereafter subjected to neutral hydrolysis. In addition to decreasing the overall time required to effect complete hydrolytic depolymerization, this process additionally permits the use of a smaller hydrolysis vessel, thereby reducing the fabrication cost of the hydrolysis unit.

REFERENCES:
patent: 3488298 (1970-01-01), Barkley et al.

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