Drug – bio-affecting and body treating compositions – Anti-perspirants or perspiration deodorants
Reexamination Certificate
2001-05-02
2003-10-14
Dodson, Shelley A. (Department: 1616)
Drug, bio-affecting and body treating compositions
Anti-perspirants or perspiration deodorants
C424S067000, C424S400000, C424S401000
Reexamination Certificate
active
06632421
ABSTRACT:
The present invention relates to a deodorant composition comprising at least one water-soluble zinc salt as odour-absorbing agent, in particular a composition comprising the zinc salt as the sole odour-absorbing agent, and to the use of these compositions in human topical application.
It also relates to a deodorization process which makes use of the composition and more especially to a process for treating human axillary smells comprising the application to the axillary surface of an effective amount of the composition.
It is well known in the cosmetics field to use deodorant products in topical application containing active substances of antiperspirant type or of bactericidal type to decrease, indeed remove, the generally unpleasant axillary smells.
Antiperspirant substances have the effect of limiting the flow of sweat. They are generally composed of aluminium salts which, on the one hand, are irritating to the skin and which, on the other hand, decrease the flow of sweat by modifying the cutaneous physiology, which is unsatisfactory.
Bactericidal substances, by inhibiting the development of the cutaneous flora responsible for axillary smells, have the disadvantage of not being active with respect to the smell of the sweat already present. These bactericidal products, the most widely employed of which is triclosan (5-chloro-2-(2,4-dichlorophenoxy)phenol), are therefore insufficiently effective on a long-term basis.
With the aim of obtaining a longer-lasting effectiveness, the search is under way for deodorant products that exert an odour-absorbing effect, that is to say products that are capable of capturing and retaining within themselves the molecules responsible for unpleasant smells (this definition is given in the work “Cosmetic Science and Technology Series”, 1988, Volume 7, Chap. 10-IIIc). These products have the effect of decreasing, to a greater or lesser extent, the smell of sweat already present and do not exhibit the disadvantages of the active substances previously employed in deodorant compositions.
From this viewpoint, certain zinc salts have already been provided. In particular, zinc salts of polycarboxylic acids described in U.S. Pat. No. 4,425,321, which is incorporated herein by reference, and in particular those of dimerginic acid and those of trimerginic acid, which may or may not be hydroxylated, are known.
Nevertheless, such zinc-based odour-absorbers are still not very satisfactory due to the fact that their insolubility in water makes it difficult to formulate them in water-based compositions, which is often the case for formulations intended in particular for a cosmetic use.
After much research directed at this question, the inventors have now discovered, entirely unexpectedly and surprisingly, that water-soluble zinc salts also exhibit the property of absorbing unpleasant smells, without the disadvantages of the active substances previously employed in deodorant compositions and with the advantage of being water-soluble in advantageous proportions that are sufficient for being easily formulable, in particular in water-based cosmetic compositions for human topical application. These compositions are, in addition, non-toxic and non-irritating. This discovery underlies the present invention.
The subject of the present invention is thus a new deodorant composition comprising, as odour-absorbing agent, at least one water-soluble zinc salt.
Another subject of the invention is a deodorant composition comprising, as sole odour-absorbing agent, one or a number of water-soluble zinc salts.
Another subject of the invention is a deodorant composition in the form of an emulsion, comprising at least one water-soluble zinc salt in an amount effective to absorb odor and further comprising water in an amount sufficient to form the emulsion.
Another subject of the invention is a deodorant composition having at least 2 phases and comprising at least one water-soluble zinc salt.
Another subject of the invention is the use of the compositions, more especially in, or for the manufacture of, cosmetic products intended for human topical application.
Another subject of the invention is the use of at least one water-soluble zinc salt as (preferably sole) an odour-absorbing agent, or for the manufacture of, a deodorant composition, in particular a cosmetic composition.
Another subject of the invention is a method of preparing a deodorant composition in the form of an emulsion comprising the step of including in the composition at least one water-soluble zinc salt in an amount effective to absorb odor and water in an amount effective to form an emulsion.
Still another subject of the invention is a deodorization process that makes use of the composition, and more particularly a process for treating human axillary smells, that comprises the application to the axillary surface of an effective amount of the composition.
Within the meaning of the present invention, water-soluble zinc salts is understood to mean zinc salts of organic or inorganic acids, the solubility of which in water, expressed as percentage by weight of Zn ion, is greater than or equal to about 0.3. Water-soluble zinc salts that are particularly preferred according to the present invention are zinc pyrrolidonecarboxylate (more commonly known as zinc pidolate), zinc sulphate, zinc chloride, zinc lactate, zinc gluconate and zinc phenolsulphonate. Among the salts mentioned above, preference is still more particularly given to the use, according to the present invention, of zinc pyrrolidonecarboxylate.
In the deodorant compositions according to the present invention, the water-soluble zinc salt is generally present in proportions by weight, calculated as Zn ion, preferably ranging from approximately 0.01 to approximately 10%, more preferably ranging from approximately 0.1 to approximately 5%, and better still ranging from approximately 0.1 to 2% with respect to the whole of the composition.
According to a preferred embodiment of the compositions according to the invention, the latter do not contain, or do not substantially contain, odour-absorbing agents other than water-soluble zinc salts.
The deodorant compositions of the present invention are conventionally formulated according to the applications for which they are intended. When they are intended for a cosmetic use, they are preferably formulated in a cosmetically acceptable vehicle that can in particular be essentially aqueous and can contain C
1
-C
4
monoalcohols, preferably ethanol, to accelerate evaporation of the product, and/or C
2
-C
6
polyols, preferably glycerol, propylene glycol or sorbitol, as moisturizing agents, in a proportion by weight ranging from 0 to approximately 50%. They can also be formulated as a water-in-oil or oil-in-water emulsion or as a water-in-oil-in-water triple emulsion (such emulsions are known and described, for example, by C. Fox in “Cosmetics and Toiletries”, Vol. 101, November 1986, pages 101-112, specifically incorporated by reference herein), in which case the water-soluble zinc salt is present in the aqueous phase of the emulsion. According to a preferred embodiment of the present invention, the compositions are formulated in the form of a water-in-silicone emulsion, which makes it possible according to the invention to reinforce the effectiveness of the water-soluble zinc salt as odour-absorbing agent in comparison with an aqueous formulation containing an equivalent amount of the same water-soluble zinc salt. The water-in-silicone emulsions according to this preferred embodiment comprise: (i) a dispersed aqueous phase and (ii) a continuous silicone fatty phase comprising (a) a volatile dimethicone and (b) a silicone emulsifying agent.
(i) Aqueous Phase
The aqueous phase of these emulsions can contain, in addition to the water-soluble zinc salt as odour-absorbing agent, other ingredients, such as humectants, for example polyols, stabilizers, for example citric acid or lactic acid, and optionally C
1
-C
4
monoalcohols, such as ethanol.
(ii) Continuous Fatty Phase
In the continuous silicone fatty phase of these emulsio
Ascione Jean-Marc
Forestier Serge
Rollat-Corvol Isabelle
Dodson Shelley A.
Finnegan Henderson Farabow Garrett & Dunner L.L.P.
L'Oreal
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