Dentin adhesive containing 2-hydroxyethyl methacrylate and ester

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...

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Details

524317, 525 59, 528271, 528361, 433215, C08L 6700, C08L 6707, A61C 500

Patent

active

053730348

ABSTRACT:
A primer composition has been discovered which improves bonding of dentin and filler resin. The primer composition disclosed in the present invention contains, in weight ratio of 20:1 to 5:1, of 2-hydroxyethyl methacrylate and the esterification product of polyvinyl alcohol and acryloyl chloride. The weight average molecular weight of polyvinyl alcohol ranges from 60,000 to 85,000 with residual acetyl content is less than 10%. The esterification of OH group in polyvinyl alcohol ranges from 5 to 40 mole percent. The present invention does not contain glutaraldehyde, but provides greater bonding strength.

REFERENCES:
patent: 5264513 (1993-11-01), Ikemura et al.
Hasegawa T. et al., "Bonding Stability and Shelf Life of Gluma" Dental Materials/May 1989, 151.
Henderson L. J. et al., "Gluma dentin adhesive: Effectiveness and shelf life" Dental Material/Sep. 1989, 307.
Asmussen E. et al., "Bonding of restorative resins to dentine promoted by aqueous mixtures of aldehydes and active monomers" International Dental Journal 1985 vol. 35, 160-165.
Munksgaard E. C. et al., "Bond Strength Between Dentin and Restorative Resins Mediated by Mixtures of HEMA and Glutaraldehyde" J. Dent Res 63 (8): 1087-1089, Aug., 1984.
Asmussen Erik et al., "Adhesion to dentin by means of Gluma resin" Scand J. Dent Res 1988; 96: 584-9.

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