Dental composition and artificial tooth with the use of...

Dentistry – Prosthodontics – Tooth construction

Reexamination Certificate

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Reexamination Certificate

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06196843

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a dental composition and an artificial tooth with the use of said dental composition, In more detail, the invention relates to a dental composition which has good mechanical properties and mechanical machinability, which is superior in color stability, coloring resistance and aesthetic merit, and which is suitable for an artificial tooth, as well as to an artificial tooth by the use of said dental composition.
2. Description of the Prior Art
An artificial tooth is generally required to satisfy various requirements, for example, good mechanical properties such as wear resistance, strength, and impact resistance; good mechanical machinability; good color stability and coloring resistances; superior aesthetic merit; absence of biological detrimentality; and a good biological compatibility etc.
As artificial teeth, resin teeth comprising polymethylmethacrylate as a main component, hard resin teeth comprising multifunctional methylmethacrylate and inorganic fillers, as well as porcelain teeth have been developed and are in use.
As resin teeth, those comprising methacrylate polymers and copolymers mainly consisting of methacrylate have been developed and are in use. Although those are cheap and superior in aesthetic merit, color stability and impact resistance, they have low and insufficient wear resistance. Since resin teeth are exposed to a high temperature when ground with abrasives such as carborundum point or stamp bur for occlusal adjustment by means of a laboratory machine etc., resins are molten and adhered to the abrasives, which lowers grinding efficiency extremely. Further, even though there are some differences in occlusive force during mastication of food between different persons, the force is said to correspond generally to the weight of the person. Thus, when such occlusive force being subjected to a tip of a tooth, occlusive pressure at the tip of the tooth caused by the occlusive force becomes vast. From the above-mentioned causes, there may be easily formed wear and damage in resin teeth due to occlusion during mastication or use of a tooth brush etc. Further, tooth shape may be changed by strong mastication, thus it is difficult to use it stably for a long period of time.
With a view to overcoming the defects of resin teeth; hard resin teeth have been developed Those are composite materials (composite resins) in which polymerized and hardened resins are used as matrices. The resins are prepared by kneading and dispersing inorganic fillers into multifunctional methacrylate monomers and/or oligomers. The hard resin teeth have an aesthetic merit necessary for anterior teeth and sufficient mechanical strength against occlusive pressure for molars. Further, they have preferably improved wear resistance since the inorganic fillers have high hardness. However, the inorganic fillers dispersed in the matrix resins are dug up and exposed at the surface by form-correction or polishing, or are peeled off the surface. Thus, the surface of the hard resin tooth becomes rough, resulting in deteriorated touch with the tongue. Further, dental plaque or dental calculus is deposited in voids formed by peeling of the inorganic fillers from the hard resin tooth. Thereby, the hard resin tooth may be colored. Since the multifunctional methacrylate polymer itself has poor color stability, it may be discolored during use in the mouth. Additionally, since the hard resin tooth has higher hardness than the conventional resin tooth, fractures or chips may be formed during laboratory procedures and a cusp may be easily fractured by strong mastication in the mouth.
A porcelain tooth, one kind of ceramic artificial teeth used for a long time, is high in wear resistance, excellent in aesthetic merit, color stability and coloring resistance, free from biological detrimentality or irritation in the oral condition, good in touch with the tongue, and is a stable dental material exhibiting no change in material quality even in long-term use. However, as compared with resin and hard resin teeth, it is defective in that it is high in cost, poor in elasticity, low in impact resistance because of brittleness, and tends to suffer cracking and fracture. Further, there occurs a considerable shrinkage caused by firing, thus making it difficult to accurately sinter into a prescribed shape. It is the usual practice to use a porcelain tooth after firing, polishing and form-correction. Thermal stress during correction polishing causes microcracks. And those microcracks grow larger through repetition of occlusive pressure during mastication of food and impact caused by chewing hard food, thus resulting in fatigue breakage, or under an excessive occlusion load, in breakage. When a porcelain tooth is used, mechanical retention means such as a pin or a retaining hole is provided in the porcelain tooth to achieve an integral connection of the porcelain material and the denture base resin, because of a very low adhesion between the porcelain tooth and the denture base resin serving as a denture or a support. Such retention means tends however to be subjected to stress concentration, and a defective attachment causes cracks in the surrounding denture base resin or breakage of the porcelain tooth after attachment in the mouth. The porcelain tooth may also tend to come off the denture base resin. For these reasons, manufacture of a satisfactory denture using a porcelain tooth requires skill and a high cost.
SUMMARY OF THE INVENTION
Thus, there are advantages and disadvantages in the use of resin teeth, hard resin teeth and porcelain teeth. There is therefore desired development of an artificial tooth having balanced advantages of resin teeth, hard resin teeth and porcelain teeth and also with decreased disadvantages.
The present invention was created as a result of extensive studies carried out in view of the circumstances as described above, and has an object to provide a dental composition which can maintain superior color stability, coloring resistance and aesthetic merit, which has superior characteristics in bending strength, impact strength, hardness and wear resistance etc., and which is suitable for an artificial tooth, as well as to an artificial tooth by use of said dental composition.
The foregoing and other objects, features and advantages of the present invention will become clear from the following detailed description.
DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
The dental composition and the artificial tooth according to the invention in order to accomplish the above-mentioned object are described as follows. Herein, in order to illustrate the present invention, materials used are shown as follows for convenience.
Raw material (A): at least one monomer and/or oligomer selected from methacrylates and acrylates.
Raw material (B): an uncrosslinked polymer selected from the group consisting of homopolymers of methacrylates, acrylates and styrene; copolymer of at least two monomers selected from methacrylates, acrylates and styrene; mixture of the homopolymers; mixture of the copolymers; and mixture of the homopolymer(s) and the copolymer(s).
Raw material (C): a crosslinked polymer selected from the group consisting of homopolymers of methacrylates, acrylates and styrene; copolymer of at least two monomers selected from methacrylates, acrylates and styrene, mixture of the homopolymers; mixture of the copolymers; and mixture of the homopolymer(s) and the copolymer(s).
Raw material (D): an organic and inorganic filler complex,
Raw material (E): an inorganic filler.
Therefore, the dental composition according to the invention comprises a raw material (A), a raw material (B), a raw material (C) and a raw material (D).
Thus, a dental composition which can maintain superior color stability, coloring resistance and aesthetic merit for a long period of time, which is superior in bending strength, impact strength, hardness and wear resistance etc., and which has balanced characteristics suitable for an artificial tooth is provided.

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