Drug – bio-affecting and body treating compositions – Dentifrices
Reexamination Certificate
2000-05-05
2003-06-10
Jarvis, William R. A. (Department: 1614)
Drug, bio-affecting and body treating compositions
Dentifrices
C424S052000, C433S216000
Reexamination Certificate
active
06576225
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention is related to a dental care composition to be used for the prophylactic dental hygiene. Such dental care compositions generally include three different types of pastes, classified according to hardness (hard, medium, soft). The structure of these pastes is not comparable to a conventionally used toothpaste and corresponds rather to a nearly crumbly polishing paste. This crumbly structure is necessary when the dentifrice is used in the buccal cavity with a polishing device in order to avoid loss of substances by e.g. splashing. These pastes are used by dental hygienists as a supplement to daily dental care in order to remove stubbornly adhering dental plaque. This additional treatment is intended to support oral hygiene in such a manner that caries are reduced, thus rendering dental treatment almost superfluous.
2. Description of the Prior Art
A water containing paste of such a kind which contains precipitated silicic acid as a major cleaning body component, but also perlite, has been disclosed in EP-A-0,268,763. Another variant which imperatively contains hydrophobic pyrogenic silicic acid as a stabilizer for perlite, is described in EP-A-0,528,756, which is incorporated in the description by reference.
During their application, these dental care compositions, also called prophylactic pastes, show several problems:
The consistence that has a tendency to crumbling renders difficult the taking out from supply or portion recipients and the application onto the dental cleaning tools (paste carriers) of the dental hygienist.
For the same reason, it is impossible to portion the known prophylactic pastes into the preferred amounts for each single application without problems.
Finally, the known prophylactic pastes have the known tendency, when coming into contact with the saliva of the patient, to be mixed with the saliva and to be flung from the paste carrier. These rotating tools are for example working in a speed range of from 2,000 to 6,000 rpm. However, it is often recommended to avoid rotational speeds of more than 3,000 rpm since otherwise the paste flings away from the tool.
The first and major object of the present invention is to provide a dental care composition for the above indicated purpose of prophylactic dental hygiene which has improved application properties. A further object of the invention consists in providing a such paste of improved acceptance by the dental hygienist and the patient. Another object of the invention is to provide a method for the cleaning treatment of teeth in the prophylactic dental hygiene, comprising using a grinding or polishing instrument of the professional dental prophylaxis.
SUMMARY OF THE INVENTION
The objective of the invention is fulfilled by a new dental care composition which contains (A) a cleaning body comprising a major proportion of plate shaped, flat or curved rock particles, (B) an effective amount of at least one nonionic surfactant, and (C) at least one emulsifying agent, the combined amounts of cleaning body (A) and of surfactant (B) being at least 30% by weight of the dental care composition, the proportion of emulsifying agent (C) being comprised between 0 and 20% by weight of the dental care composition.
The method of the invention is characterized by the use of the dental care composition defined in the foregoing paragraph.
Preferred or special embodiments of the present invention will become evident from the following description of the implementation of the invention and from the dependent claims.
The paste according to the invention is thus characterized in that it contains a cleaning or polishing body essentially comprising sharp edged, plate shaped particles of a rock, preferably perlite, and a nonionic surfactant.
The nonionic surfactant fulfills at the same time the function of a solvent. Its nature and amount therefore adjust the flow properties of the dental care composition. It has been found that a polyethylene glycol known under the common name (INN) “Macrogol” which is a polyether, is particularly appropriate. It is believed that the nonionic surfactant forms a kind of hull or shell at least around the rock particles, this hull acting simultaneously as a bonding agent to the remaining free molecules of the surfactant. As a result of these considerations, it can be understood that especially surfactants of moderately long chain have a particularly good effectiveness. Tests have also shown that the use of species of too a long chain will result in a loss of softness of the paste which becomes too “dry” and crumbly. It has furthermore been found that generally the addition of an emulsifyer or an emulsifyer mixture will be required, especially in cases where, in spite of a careful selection of the surfactant, the required softness of the dental care composition cannot perfectly be obtained.
Plate shaped polishing body particles have the tendency of aligning during the cleaning application in such a way that the formation of grooves in the tooth surface and other undesired effects of the action of prophylactic pastes comprising sharp-edged, rather spheroidal particles are significantly reduced. It can thus be expected, starting from these findings, that still other natural or synthetic mineral materials, namely rocks, which are able to be comminuted to plate-shaped particles of appropriate size and shape, may be used instead of the prototype perlite, e.g. bentonite, the zeolithes, vermiculite, pumice stone. The plates may also be curved; perlite particles are shell shaped in the manner of eggshell fragments. A remarkable property of perlite is its ability that its particles will break into pieces during the application but remain nevertheless sharp-edged and conserve their cleaning action in becoming smaller and smaller, analogously to a grinding material turning from a coarse state into increasingly finer ones.
Further details regarding the use of perlite and other rocks in prophylactic pastes can be taken from the published European patent application No. EP-A-0,528,756.
DETAILED DESCRIPTION OF THE INVENTION
The invention shall now be explained in more detail by the description of preferred embodiments thereof. If not other-wise indicated, all percentages in the present document are by weight.
A dental care composition according to the invention comprises at least the following characteristic components:
Perlite (expanded)
10-80% by weight,
preferably 35-55%
Macrogol
20-80% by weight,
preferably 40-50%
Emulsifyer or emulsifier
0-20% by weight,
mixture
preferably 1-10%
Additives and active
0-20% by weight,
substances
preferably 0-10%
Fillers
0-70% by weight.
The substance Macrogol is a commercially available product having a defined molecular weight. It assumes as a principal component the function of the otherwise present liquid such as water, and its amount and nature influence the rheology, in particular the viscosity and the softness. The present paste is essentially free from water and other low molecular substances which are liquid at normal temperature (298 K) and usable as solvents such as ethanol, propylene glycol, glycerol, normally present in known dental care compositions. “Low molecular” preferably means in this respect a maximal molecular weight of about 100.
Macrogol species having a molecular weight of from 200 to 1,000, preferably of from 200 to 600, have proven as particularly appropriate. The commercially available products having a narrowly specified average molecular weight range or even those with definite molecular weight may be used alone or in admixture. It is to be expected that a still finer adjustment of the application properties, especially of the rheology, will be obtained by an appropriate blending of surfactants having different molecular weights. For example, when the amount of higher molecular components is increased, a higher viscosity is to be expected.
The perlite which can be used has an average particle diameter of about 30 &mgr;m, 99% thereof being present within the size range of from 1 &mgr;m
Balmelli Patrizia
Kilcher Beat
Silber Gert
Von Weissenfluh Beat A.
Jagoe Donna
Jarvis William R. A.
KerrHawe SA
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