Dense star polymers having two dimensional molecular diameter

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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525410, 525416, 525418, 525451, 528310, 528332, 528350, 528373, 528271, 528374, 528376, 528397, 528403, 528405, 528425, C08G 6900

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045873291

ABSTRACT:
Dense star polymers having terminal group densities greater than conventional extended star polymers exhibit greater and more uniform reactivity than their corresponding conventional star polymers. For example, a third generation, hydroxy-terminated polyether dense star polymer can be prepared from pentaerythrityltetrabromide and 4-hydroxymethyl-2,6,7-trioxabicyclo[2.2.2]-octane which has a molecular volume less than 80 percent of the volume of a conventional extended star polymer made from similar materials. Such dense star polymers are useful as demulsifiers for oil/water emulsions, wet strength agents in the manufacture of paper, proton scavengers, calibration standards for electron microscopy, and agents for modifying viscosity in aqueous formulations such as paints.

REFERENCES:
patent: 4507466 (1985-03-01), Tomalia et al.
Tomalia et al., Polymer Journal, vol. 17, No. 1, pp. 117-132 (1985).

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