Denitrification method

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Nitrogen or nitrogenous component

Reexamination Certificate

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C423S239200

Reexamination Certificate

active

07393512

ABSTRACT:
A process for reducing the content of NOxand N2O in gases, in particular in process gases and offgases, which comprises the measures: a) addition of at least one nitrogen-containing reducing agent to the NOx- and N2O-containing gas in at least the amount required for complete reduction of the NOx; b) addition of a hydrocarbon, of carbon monoxide, of hydrogen, or of a mixture of one or more of these gases to the NOx- and N2O-containing gas for the reduction of the N2O; and c) introduction of the gas mixture into at least one reaction zone at temperatures of up to 450° C., which contains one or more iron-laden zeolites. The process can be used, in particular, in nitric acid production, for offgases from power stations or for gas turbines.

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patent: 6056928 (2000-05-01), Fetzer et al.
patent: 2004/0109805 (2004-06-01), Schwefer et al.
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patent: WO 01/51182 (2001-07-01), None
patent: WO-02/087733 (2002-11-01), None
Derwent Abstract of AN-1997-113390. XP-002242664 & JP9000884 A (Babcock-Hitachi KK) (Jan. 7, 1997).
Kogel, M. et al., “Simultaneous Catalytic Removal of NO and N2O using Fe-MFI”, Journal of Catalysis 182:470-478, XP-000996158 (1999).
Kameoka, S. et al, “Selective catalytic reduction of N2O with methane in the presence of excess oxygen over Fe-BEA zeolite” Chem. Commun.: 745-746 (2000).

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