Dehydrohalogenation of haloethyl brominated benzenes

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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570200, 502164, C07C 1734

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active

046863117

ABSTRACT:
A process for the preparation of bromostyrenes which comprises aqueous alcoholic alkali dehydrohalogenation of a 1-haloethyl bromobenzene, a 2-haloethyl bromobenzene, or a 1-methyl-2-haloethyl brominated benzene in the presence of a phase transfer catalyst at a temperature of between about 0.degree. C. and about 150.degree. C. The bromostyrenes have the particular utility as a comonomer for the preparation of a co-polymer exhibiting a flame retardancy. Both bromostyrenes and brominated alpha-methyl styrenes are formed.

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