Dehydrogenative silylation process of organic compounds having a

Details Dehydrogenative silylation process of organic compounds having a Dehydrogenative silylation process of organic compounds having a

1989-06-22

1991-09-10

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

556410, 556413, 556442, 556470, 544 69, C07F 708, C07F 718, C07F 710, C07D20500

Patent

active

050475266

ABSTRACT:
A dehydrogenative silylation process of organic compounds having active hydrogen which comprises reacting an organic compound having active hydrogen with t-butyldimethylsilane in the presence of a catalyst which is a metal of Group VIII of the periodic table or its compound. The reaction may be carried out in a solvent. When the organic compound is a strongly acidic compound, the reaction may be carried out without use of any catalyst.

REFERENCES:
Noll, "Chemistry and Technology of Silicones", Academic Press, N.Y. (1968), p. 92.
"A Stereocontrolled Synthesis of (+)-Thienamycin", by Salzmann et al.; J. Am. Chem. Soc. 1980, 102, 6161-6163.
"Protection of Hydroxyl Groups as tert-Butyldimethylsilyl Derivatives", by Corey et al.; Journal of the American Chemical Society; Aug. 23, 1972; pp. 6190 & 6191.

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