Dehydrogenation reactions

Chemistry of hydrocarbon compounds – Alicyclic compound synthesis – By dehydrogenation

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585418, 585419, 585420, 585430, 585434, 585629, 585662, 502182, 502184, 502185, C07C 532, B01J 2118

Patent

active

044476655

ABSTRACT:
A method is disclosed for dehydrogenating a parafinic or naphthenic compound and for dehydrocyclizing a paraffinic compound comprising a straight chain of at least 5 carbon atoms, comprising: contacting an aforesaid compound under dehydrogenation conditions comprising a temperature in the range of from about 465.degree. C. to about 650.degree. C. with an active carbon catalyst having a cage-like structure and a BET surface area of at least 800 square meters per gram and a bulk density of at least 0.1 gram per cubic centimeter and comprising a substantially uniform dispersion of a metal, metal-containing material, or both in a porous carbon matrix, wherein the dispersed metal and metal in the dispersed metal-containing material are each a transition metal and wherein the total concentration of dispersed metal and dispersed metal-containing material is from about 0.001 to about 30 weight percent, calculated as the elemental metal and based on the weight of the catalyst.

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