Dehydrogenation of dehydrogenatable hydrocarbons

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – Having alkenyl moiety – e.g. – styrene – etc.

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585319, 585440, 585444, 585654, 585659, 585660, C07C 540, C07C 548

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044356072

ABSTRACT:
Dehydrogenatable hydrocarbons may be subjected to a dehydrogenation reaction in which the hydrocarbons are treated with a dehydrogenation catalyst such as a modified iron compound in the presence of steam in a multi-catalyst bed system. The reaction mixture containing unconverted hydrocarbon, dehydrogenated hydrocarbon, hydrogen and steam is then contacted with a selective oxidation catalyst such as a noble metal of Group VIII of the Periodic Table, a metal of Group IVA of the Periodic Table and, if so desired, a metal of Group IA or IIA of the Periodic Table composited on a highly porous inorganic support. The oxidation catalyst will selectively oxidize the hydrogen to improve the combustion thereof and supply the necessary heat required for a subsequent dehydrogenation treatment.

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patent: 3742078 (1973-06-01), Hayes
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patent: 3855330 (1974-12-01), Mendelsohn et al.
patent: 3856870 (1974-12-01), Hayes
patent: 3904703 (1975-09-01), Lo et al.
patent: 4177218 (1979-12-01), Antos

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